03.17.2005 01:00

Einstein's paper on the photoelectric effect: 100 years ago today


On March 17, 1905, Albert Einstein submitted his paper, Über einen die Erzeugung und Verwandlung des Lichtes betreffenden heuristischen Gesichtspunkt (Concerning an Heuristic Point of View about the Creation and Conversion of Light (pdf)). This is the paper for which he received the 1921 Nobel Prize in Physics "for his services to Theoretical Physics, and especially for his discovery of the law of the photoelectric effect", not for Brownian motion, not for special relativity, not for general relativity, not for the famous equation E = mc2.

Max Planck had hypothesized that energy came in discrete packets, which he called quanta.
[T]he problems of radiation processes engaged his attention and he showed that these were to be considered as electromagnetic in nature. From these studies he was led to the problem of the distribution of energy in the spectrum of full radiation. Experimental observations on the wavelength distribution of the energy emitted by a black body as a function of temperature were at variance with the predictions of classical physics. Planck was able to deduce the relationship between the energy and the frequency of radiation. In a paper published in 1900, he announced his derivation of the relationship .... The energy for a resonator of frequency v is hv where h is a universal constant, now called Planck's constant.
Max Planck -- Biography. Planck received the 1918 Nobel Prize in Physics for this discovery: "in recognition of the services he rendered to the advancement of Physics by his discovery of energy quanta".

Maxwell's equations and classical thermodynamics assumed that the range of possible energies was continuous, consistent with the view that electromagnetic energy propagated through space as waves.

Physicists knew that when ultraviolet light shined upon certain metals, electrons were ejected from the material. But the number of electrons ejected depended on the intensity of the light, and the energy of the electrons depended on the frequency, not the intensity, of the light, facts difficult to explain under classical physical theory, but not difficult if the ultraviolet light and the electrons were quanta, and that only certain energy states were permitted: the intensity of the light is the flux (concentration, or number passing through an area) of the quanta, and the energy is Planck's equation.

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